Doc:Dye

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Anthraquinone

For alzarin and kermisic acid, KAl(SO4)2.12H2O (alum) is the common mordant.

Name CAS Color Source
Alizarin [72-48-0] red Madder plants in Rubiaceae, especially Rubia tinctorum, and R. peregrina produce a glycoside (ruberythric acid [152-84-1]) in roots (1-2 %).
Kermisic acid [476-35-7] red Kermes ilicis (oriental shield louse), which infest the holm oak Quercus ilex and the shurub oak Q. coccifera.
Carminic acid [1260-17-9] red Daetylopius coccus (cochineal insect) in family Coccidae, order Homoptera. Carmine [1390-65-4], the only animal-derived food dye, is its aluminum lake. Aztecs red. Nowadays Peru and the Canary islands are the main source.
Laccaic acid [6219-66-5] red Coccus laccae (small insect in India and SE Asia)

Naphtoquinone

Name CAS Color Source
Lawsone [83-72-7] yellow Lawsone alba (henna or Egyptian privet). Mohammed dyed his beard with henna.
Lapacol [84-79-7] yellow Tecoma species (tree in West Indies and South America)
Juglone [481-39-0] brown Juglans cinerea (butternuts), J. regia (Persian salnuts), J. nigra (black walnuts) in Juglandaceae
Alkannin [577-88-4] red Anchusa tinctoria, Alkanna tinctoria in Boraginaceae
Shikonin [517-89-5] red Lithospermum erythrorhizon in Boraginaceae. The color of Tokyo violet. Its racemate is Shikalkin [54952-43-1].

Benzopyrone

Flavone

Flavone dyes require a mordant that chelate positions

Name CAS Color Source
quercetin [117-39-5] yellow
kaempferol [520-18-3] yellow
chrysin [480-40-0] yellow
luteolin [491-70-3] yellow Oldest known European dye, originally from Reseda luteola. The yellow color of Vestal Virgins in ancient Romans, and green colors (with indigotin) named as Lincoln green and Saxon green.

Anthocyanin

Anthocyanins are not used as industrial dyes because of its pH sensitivity. Only two deoxyanthocyanidins were formerly used as dyes.

Name CAS Color Source
carajurin [491-93-0]  ?
dracorhodin [643-56-1]  ?

Others

Name CAS Color Source
Logwood [8005-32-2] black Haematoxylon species. Oxidized form is haematein [475-25-2], whose leuco form is haematoxylin [517-28-2].
Brazilwood [8005-32-1] red Caesalpina species. Oxidized form is brazilein [600-76-0], whose leuco form is brazilin [474-07-7].

Indigoid

Name CAS Color Source
indigotin [482-89-3] blue Indigo tinctoria and I. suffruticosa (2-4%). Its precursor is indican [487-60-5], dextrose derivative of indoxyl [480-93-3]. Indigo came to Europe only after 12th century, where Isatis tinctoris (woad) had been used, and became widespread as late as in 17th century.
6,6'-bromoindigotin
or Tyrian purple
[19201-53-7] ? [19201-58-7] purple Mulex species (e.g. M. brandaris, M. trunculus) and Purpura species (mollusk) Each mollusk produces only 0.12 mg. Its precursor is tyriverdin and tyrindoxyl sulfate [74626-31-6].

Carotenoid

Betalaine

Betalaines contain two groups of pigments: the red betacyanins and the yellow betaxanthins. Both are found in beets (Beta vulgaris). Although unaffected by pH, they are heat sensitive.

Name CAS Color Source
betanin [7659-95-2] yellow Its aglycon is batanidin [32729-84-8].

Others

Name CAS Color Source
curcumin
or turmeric
[458-37-7] yellow Curcuma tinctoria. The dye is oil-soluble and requires no mordant.
chlorophyll [8049-84-1] green Water-insoluble. By hydrolysis with sodium hydroxide, chlorophyllin, phytol and methanol result. Chlorophyllin salt is heat stable.
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