Category:TP5
From Metabolomics.JP
(Difference between revisions)
m (→{{Bilingual|セスキテルペン合成酵素|Sesquiterpene Synthase}}) |
m (→{{Bilingual|セスキテルペン合成酵素|Sesquiterpene Synthase}}) |
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<!---FARNESYL---> | <!---FARNESYL---> | ||
|- | |- | ||
− | |rowspan=" | + | |rowspan="7" align="center"| farnesyl cation<br/>[[Image:Farnesyl cation.png|100px]] |
|colspan="2"| | |colspan="2"| | ||
{| | {| | ||
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|} | |} | ||
|- | |- | ||
− | |rowspan="3"|(E,E)- | + | |rowspan="3"|(E,E)-germacradiene<br/>[[Image:(E,E)-Germacradienyl cation.png|100px]] [[Image:Germacrene A.png|80px]] |
− | + | * germacrane | |
− | * lepidozane | + | * lepidozane |
− | | | + | * bicyclogermacrane |
+ | | eudesmane (= selinane)<br/>[[Image:Eudesmanyl cation.png|100px]] [[Image:beta-Selinene.png|80px]] | ||
* cycloeudesmane | * cycloeudesmane | ||
* elemane ... 7,8 seco form | * elemane ... 7,8 seco form | ||
* emmotin ... 14(10→1) abeo form | * emmotin ... 14(10→1) abeo form | ||
− | |||
* farfugin ... 14(10→9) abeo form | * farfugin ... 14(10→9) abeo form | ||
* gorgonane 11(7→6) abeo form | * gorgonane 11(7→6) abeo form | ||
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| vetispiradienyl_cation [[Image:Vetispiradienyl_cation.png|80px]] → spirovetivane (= vetispirane) | | vetispiradienyl_cation [[Image:Vetispiradienyl_cation.png|80px]] → spirovetivane (= vetispirane) | ||
|- | |- | ||
− | | | + | | eremophilane (= 14(10→5) abeoeudesmane)<br/>[[Image:Eremophilenyl cation.png|100px]] |
− | |||
* aristolane ... 6,11-cyclo form [[Image:5-epi-Aristolochene.png|80px]] | * aristolane ... 6,11-cyclo form [[Image:5-epi-Aristolochene.png|80px]] | ||
* chiloscyphane ...8(7→6) abeo form | * chiloscyphane ...8(7→6) abeo form | ||
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* valerenane ... 8(7→6) abeo form | * valerenane ... 8(7→6) abeo form | ||
| | | | ||
− | + | Cycloguaiane | |
* cubebane ... 1,6-cyclo form | * cubebane ... 1,6-cyclo form | ||
* ivaxillarane ... 8,10-cyclo form | * ivaxillarane ... 8,10-cyclo form | ||
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* patchoulane ... 1,11-cyclo form | * patchoulane ... 1,11-cyclo form | ||
|- | |- | ||
− | |rowspan="2"| (E,E)- | + | |rowspan="2"| (E,E)-humulane<br/>[[Image:(E,E)-Humulyl cation.png|100px]] |
− | + | ||
* bicyclohumulane | * bicyclohumulane | ||
− | | | + | | africanane<br/> |
* [http://stoltz.caltech.edu/seminars/2009_Henry.pdf africanane]) | * [http://stoltz.caltech.edu/seminars/2009_Henry.pdf africanane]) | ||
|- | |- | ||
− | | | + | | caryophyllane<br/> [[Image:(E)-beta-Caryophyllene.png|60px]] |
− | + | ||
| | | | ||
+ | |- | ||
+ | | [http://www.sciencedirect.com/science/article/pii/S0040402099002562 drimane] | ||
+ | * iresin | ||
+ | * coloratane | ||
+ | | | ||
<!---NEROLIDYL---> | <!---NEROLIDYL---> | ||
|- | |- | ||
− | |rowspan=" | + | |rowspan="7"| nerolidyl cation<br/>[[Image:Nerolidyl cation.png|100px]] |
− | | | + | |rowspan="2"| bisabolane<br/>[[Image:Bisabolyl cation.png|100px]] |
− | + | ||
* thujopsane [[Image:(-)-Sesquithujene.png|80px]] | * thujopsane [[Image:(-)-Sesquithujene.png|80px]] | ||
| | | | ||
− | * | + | * acorane ... 6,10-cyclobisabolane |
− | * | + | * chamigrane ... 6,11-cyclobisabolane |
− | * | + | |- |
− | + | | cuparane (= 7,11-cyclobisabolane) | |
− | + | * herbertane [[liverwort,fungi]] ... 15(3→4) abeo form | |
+ | * laurane [[Laurencia spp. (marine)]] ... 13(11→10) abeo form | ||
+ | | trichothecane <ref>Grove JF "Non-Macrocyclic Trichothecenes" Nat Prod Rep 5:187-209, 1988</ref> | ||
{| | {| | ||
| gymnomitrane | | gymnomitrane | ||
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|} | |} | ||
|- | |- | ||
− | | (Z,E)- | + | | (Z,E)-germacradiene<br/>[[Image:(Z,E)-Germacradienyl cation.png|100px]] |
− | + | | cadinane [[Image:(+)-delta-Cadinene.png|80px]] | |
− | + | * bulgarane, calamenene, muurolane, amorphane, cadalane | |
− | | cadinane (bulgarane,calamenene, muurolane, amorphane, alliacane/primnatriene | + | * alliacane/primnatriene ... 2(3→4) abeo cadinane |
− | + | * oplopane ... 3(4→5) abeo cadinane | |
− | * | + | * mutisianthol ... 6(7→8) abeo cadinane |
+ | * copaane ... 5,10 cyclo cadinane | ||
|- | |- | ||
− | |rowspan="2"| (Z,E)- | + | |rowspan="2"| (Z,E)-humulane<br/>[[Image:(Z,E)-Humulyl cation.png|100px]] |
− | | [http://onlinelibrary.wiley.com/doi/10.1002/ejoc.200300812/pdf himachalane] | + | | [http://onlinelibrary.wiley.com/doi/10.1002/ejoc.200300812/pdf himachalane] |
− | * | + | * lippifoliane |
+ | * longipinane | ||
+ | * longibornane | ||
+ | * longifolane [[Image:(+)-Longifolene.png|80px]] | ||
|- | |- | ||
− | | | + | | protoilludane |
+ | * illudane | ||
+ | * illudalane ... 4,6-secoilludane | ||
+ | * sterpurane ... 5(6→7)-abeoilludane | ||
+ | * lactarane, isolactarane, marasmane, merulane | ||
+ | | hirsutane | ||
|- | |- | ||
| cycloheptenyl cation<br/>[[Image:Cycloheptenyl cation.png|100px]] | | cycloheptenyl cation<br/>[[Image:Cycloheptenyl cation.png|100px]] | ||
| [http://www.sciencedirect.com/science/article/pii/S0031942200903273 daucane] (= carotane, isodaucane) | | [http://www.sciencedirect.com/science/article/pii/S0031942200903273 daucane] (= carotane, isodaucane) | ||
|- | |- | ||
− | | | + | | furodysin |
− | + | * furodysinin | |
− | + | ||
− | + | ||
− | + | ||
− | + | ||
− | + | ||
− | + | ||
|- | |- | ||
| Others | | Others |
Revision as of 10:31, 13 December 2011
Contents |
Sesquiterpene (C15)
Ring configuration
Germacrane
Sesquiterpenes
Biosynthesis
Overview
- References
Sesquiterpene Synthase
farnesyl diphosphate | |||||
farnesyl cation |
| ||||
(E,E)-germacradiene
|
eudesmane (= selinane)
|
vetispiradienyl_cation → spirovetivane (= vetispirane) | |||
eremophilane (= 14(10→5) abeoeudesmane)
| |||||
guaiane
|
Cycloguaiane
| ||||
(E,E)-humulane
|
africanane | ||||
caryophyllane |
|||||
drimane
|
|||||
nerolidyl cation |
bisabolane |
| |||
cuparane (= 7,11-cyclobisabolane)
|
trichothecane [1]
| ||||
(Z,E)-germacradiene |
cadinane
| ||||
(Z,E)-humulane |
himachalane | ||||
protoilludane
|
hirsutane | ||||
cycloheptenyl cation |
daucane (= carotane, isodaucane) | ||||
furodysin
| |||||
Others |
|
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