Category:TP5
From Metabolomics.JP
(Difference between revisions)
m (→{{Bilingual|セスキテルペン合成酵素|Sesquiterpene Synthase}}) |
m (→{{Bilingual|セスキテルペン合成酵素|Sesquiterpene Synthase}}) |
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<!---FARNESYL---> | <!---FARNESYL---> | ||
|- | |- | ||
− | |rowspan=" | + | |rowspan="6" align="center"| farnesyl cation<br/>[[Image:Farnesyl cation.png|100px]] |
|colspan="2"| | |colspan="2"| | ||
{| | {| | ||
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|rowspan="3"|(E,E)-germacradienyl cation<br/>[[Image:(E,E)-Germacradienyl cation.png|100px]] | |rowspan="3"|(E,E)-germacradienyl cation<br/>[[Image:(E,E)-Germacradienyl cation.png|100px]] | ||
* germacrane [[Image:Germacrene A.png|80px]] | * germacrane [[Image:Germacrene A.png|80px]] | ||
− | |||
* lepidozane and bicyclogermacrane | * lepidozane and bicyclogermacrane | ||
| eudesmanyl cation <br/>[[Image:Eudesmanyl cation.png|100px]] | | eudesmanyl cation <br/>[[Image:Eudesmanyl cation.png|100px]] | ||
* cycloeudesmane | * cycloeudesmane | ||
+ | * elemane ... 7,8 seco form | ||
* emmotin ... 14(10→1) abeo form | * emmotin ... 14(10→1) abeo form | ||
* eudesmane (previously selinane) [[Image:beta-Selinene.png|80px]] (selinene) | * eudesmane (previously selinane) [[Image:beta-Selinene.png|80px]] (selinene) | ||
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* patchoulane ... 1,11-cyclo form | * patchoulane ... 1,11-cyclo form | ||
|- | |- | ||
− | | (E,E)-humulyl cation<br/>[[Image:(E,E)-Humulyl cation.png|100px]] | + | |rowspan="2"| (E,E)-humulyl cation<br/>[[Image:(E,E)-Humulyl cation.png|100px]] |
* humulane | * humulane | ||
* bicyclohumulane | * bicyclohumulane | ||
− | |||
| africanyl cation<br/> | | africanyl cation<br/> | ||
* [http://stoltz.caltech.edu/seminars/2009_Henry.pdf africanane]) | * [http://stoltz.caltech.edu/seminars/2009_Henry.pdf africanane]) | ||
− | + | |- | |
+ | | caryophyllenyl cation<br/> | ||
+ | * caryophyllane [[Image:(E)-beta-Caryophyllene.png|60px]] | ||
| | | | ||
<!---NEROLIDYL---> | <!---NEROLIDYL---> |
Revision as of 16:50, 12 December 2011
Contents |
Sesquiterpene (C15)
Ring configuration
Germacrane
Sesquiterpenes
Biosynthesis
Overview
- References
Sesquiterpene Synthase
farnesyl diphosphate | |||||
farnesyl cation |
| ||||
(E,E)-germacradienyl cation |
eudesmanyl cation |
vetispiradienyl_cation → spirovetivane (= vetispirane) | |||
eremophilenyl cation (14(10→5) abeoeudesmane)
| |||||
guaiane
|
Cycloguaianes
| ||||
(E,E)-humulyl cation
|
africanyl cation | ||||
caryophyllenyl cation |
|||||
nerolidyl cation |
bisabolyl cation |
| |||
(Z,E)-germacradienyl cation |
| ||||
(Z,E)-humulyl cation |
himachalane (lippifoliane, longipinane, longibornane, longifolane) | ||||
(proto)illudane (illudane, sterpurane, illudalane, isolactarane, merulane, lactarane, marasmane) --> hirsutane | |||||
cycloheptenyl cation |
daucane (= carotane, isodaucane) | ||||
drimenyl cation | drimane (iresin, seco, coloratane) | ||||
furodysyl cation | furodysin (furodysinin) | ||||
chamigranyl cation | chamigrane (secochamigrane) | ||||
Others |
|
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