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Licoricesaponin C2 - Revision history
2026-09-27T00:49:42Z
Revision history for this page on the wiki
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http://metabolomics.jp/mediawiki/index.php?title=Licoricesaponin_C2&diff=107950&oldid=prev
Toyama at 06:53, 9 February 2010
2010-02-09T06:53:42Z
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<tr><td class='diff-marker'> </td><td style="background: #eee; color:black; font-size: smaller;"><div>==NMR Data==</div></td><td class='diff-marker'> </td><td style="background: #eee; color:black; font-size: smaller;"><div>==NMR Data==</div></td></tr>
<tr><td class='diff-marker'> </td><td style="background: #eee; color:black; font-size: smaller;"><div>[[Image:Licoricesaponin c2 ester hnmr.PNG|thumb|600px|none|<sup>1</sup>H-NMR Licoricesaponin C2 Methyl ester / pyridine-<i>d</i><sub>5</sub>]]</div></td><td class='diff-marker'> </td><td style="background: #eee; color:black; font-size: smaller;"><div>[[Image:Licoricesaponin c2 ester hnmr.PNG|thumb|600px|none|<sup>1</sup>H-NMR Licoricesaponin C2 Methyl ester / pyridine-<i>d</i><sub>5</sub>]]</div></td></tr>
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<tr><td colspan="2"> </td><td class='diff-marker'>+</td><td style="background: #cfc; color:black; font-size: smaller;"><div><ins style="color: red; font-weight: bold; text-decoration: none;">[[Image:Licoricesaponin c2 ester cnmr.PNG|thumb|600px|none|<sup>13</sup>C-NMR Licoricesaponin C2 Methyl ester / pyridine-<i>d</i><sub>5</sub>]]</ins></div></td></tr>
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Toyama
http://metabolomics.jp/mediawiki/index.php?title=Licoricesaponin_C2&diff=107949&oldid=prev
Toyama at 06:37, 9 February 2010
2010-02-09T06:37:58Z
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<tr><td class='diff-marker'> </td><td style="background: #eee; color:black; font-size: smaller;"><div>}}</div></td><td class='diff-marker'> </td><td style="background: #eee; color:black; font-size: smaller;"><div>}}</div></td></tr>
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<tr><td colspan="2"> </td><td class='diff-marker'>+</td><td style="background: #cfc; color:black; font-size: smaller;"><div><ins style="color: red; font-weight: bold; text-decoration: none;">==NMR Data==</ins></div></td></tr>
<tr><td colspan="2"> </td><td class='diff-marker'>+</td><td style="background: #cfc; color:black; font-size: smaller;"><div><ins style="color: red; font-weight: bold; text-decoration: none;">[[Image:Licoricesaponin c2 ester hnmr.PNG|thumb|600px|none|<sup>1</sup>H-NMR Licoricesaponin C2 Methyl ester / pyridine-<i>d</i><sub>5</sub>]]</ins></div></td></tr>
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Toyama
http://metabolomics.jp/mediawiki/index.php?title=Licoricesaponin_C2&diff=107948&oldid=prev
Toyama: New page: {{Hierarchy|{{PAGENAME}}}} {{Metabolite |SysName=(3beta,20beta)-20-Carboxy-30-noroleana-11,13(18)-dien-3-yl 2-O-beta-D-glucopyranuronosyl-beta-D-glucopyranosiduronic acid |Common Name=&&L...
2010-02-09T00:56:18Z
<p>New page: {{Hierarchy|{{PAGENAME}}}} {{Metabolite |SysName=(3beta,20beta)-20-Carboxy-30-noroleana-11,13(18)-dien-3-yl 2-O-beta-D-glucopyranuronosyl-beta-D-glucopyranosiduronic acid |Common Name=&&L...</p>
<p><b>New page</b></p><div>{{Hierarchy|{{PAGENAME}}}}<br />
<br />
{{Metabolite<br />
|SysName=(3beta,20beta)-20-Carboxy-30-noroleana-11,13(18)-dien-3-yl 2-O-beta-D-glucopyranuronosyl-beta-D-glucopyranosiduronic acid<br />
|Common Name=&&Licoricesaponin C2&&Saponin C2 from licorice&&30-Noroleanane beta-D-glucopyranosiduronic acid deriv.&&<br />
|CAS=118525-49-8<br />
|KNApSAcK=<br />
}}<br />
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==Spectroscopic Data==<br />
<br />
{| class="wikitable" style="width:80%"<br />
<br />
'''Free acid'''<br />
|-<br />
| '''M.P.''' || 249 - 251 °C <br />
|- <br />
| '''IR''' (KBr)|| 3400 (OH), 1710 (COOH), 1640 cm<sup>-1</sup><br />
|}<br />
{| class="wikitable" style="width:80%"<br />
'''Trimethyl ester'''<br />
|-<br />
| '''M.P.''' || 174 - 176 °C <br />
|- <br />
| '''<sup>13</sup>C-NMR''' (C<sub>5</sub>D<sub>5</sub>N, 22.5MHz)|| C-3) 89.5, (11) 125.5, (12) 126.7, (13) 135.8, (14) 135.8, (18) 39.9, (22) 178.4 '''GlcUA I''' (1) 104.8, (2) 84.3, (3) 76.5, (4) 72.4, (5) 77.2, (6) 169.8 '''GlcUA II''' (1)106.6, (2) 76.5, (3) 77.4, (4) 72.7, (5) 77.2, (6) 170.1 <br />
|}<br />
<small>M. Yoshikawa et al., Chem.Pharm.Bull., 36, 3710 (1988).</small></div>
Toyama